Oxygen Measurement - Electrochemical

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On the surface of a gold cathode oxygen is reduced to water kaing up electrons:

O2 + 4 H+ + 4 e-  =  2 H2O

The lead of the anode is oxidized to lead oxid releasing electrons:

2 Pb + 2 H2O  =  2 PbO + 4 H+ + 4 e-

The total reaction equation is:

O2 + 2 Pb  =  2 PbO

Using an acidic electrolyte (acetic acid) the produced lead oxide is dissolved and hus the anode is regenerated.


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